In order for any matter to absorb a photon of given energy hf , it must have a pair of energy levels separated by that amount of energy hf. If a pair of electron energy levels is available for absorption of a photon, it is also available for emission of a photon, i.e. , radiation. If it is available for an upward jump, it is available for a downward jump.
But you must be wondering that what has it got to do with me??
Enquire yourself till i hv a glass of water.....
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